Absolute Rate Constants for Iminyl Radical Reactions.

Abstract

The kinetics of cyclization of the 2-methyl-6,6-diphenyl-5-hexeniminyl radical (3) were measured by laser flash photolysis methods from 0 to 50 degrees C, and the kinetics of trapping of radical 3 by thiophenol and p-chlorothiophenol were determined between 4 and 83 degrees C by indirect methods using the unimolecular rate constants as the basis values… (More)

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