Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects.

Abstract

The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described. 
DOI: 10.1039/c3cc42125b

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Cite this paper

@article{Harding2013AbruptSC, title={Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects.}, author={David J Harding and Wasinee Phonsri and Phimphaka Harding and Ian A. Gass and Keith S. Murray and Boujemaa Moubaraki and John D. Cashion and Lujia Liu and Shane G Telfer}, journal={Chemical communications}, year={2013}, volume={49 56}, pages={6340-2} }