AN ALTERNATIVE ROUTE TO PERALKYLCYCLOPOLYSILANES: THE REACTION OF 1,2-DICHLOROTETRAALKYLDISILANES WITH LITHIUM

@article{Watanabe1983ANAR,
  title={AN ALTERNATIVE ROUTE TO PERALKYLCYCLOPOLYSILANES: THE REACTION OF 1,2-DICHLOROTETRAALKYLDISILANES WITH LITHIUM},
  author={H. Watanabe and J. Inose and K. Fukushima and Y. Kougo and Y. Nagai},
  journal={Chemistry Letters},
  year={1983},
  volume={12},
  pages={1711-1714}
}
  • H. Watanabe, J. Inose, +2 authors Y. Nagai
  • Published 1983
  • Chemistry
  • Chemistry Letters
  • The reaction of 1,2-dichlorotetraalkyldisilanes, Cl(R1R2Si)2Cl (R1=R2=iPr; R1, R2=iPr, Me; R1, R2=Me3SiCH2, Me; R1, R2=tBuCH2, Me; R1, R2=tBu, Me), with an excess amount of lithium in tetrahydrofuran gave the corresponding peralkylcyclopolysilanes, [R1R2Si]n (n=4–5), under mild conditions. 
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