A unified strategy for the synthesis of 7-membered-ring-containing Lycopodium alkaloids.

Abstract

A unique subset of the Lycopodium alkaloid natural products share a 7-membered-ring substructure and may potentially arise from a common biosynthetic precursor. To both explore and exploit these structural relationships, we sought to develop a unified biosynthetically inspired strategy to efficiently access these complex polycyclic alkaloids through the use… (More)
DOI: 10.1021/ja507740u

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