A tripyrrolylmethane-based macrobicyclic triazacryptand: X-ray structure, size-selective anion binding, and fluoride-ion-mediated proton-deuterium exchange studies.


A new class of tripyrrolylmethane-based triazacryptand with bridgehead carbons and acyclic molecules were synthesized by the Mannich reaction of tripyrrolylmethane with primary or secondary amine hydrochloride and formaldehyde, respectively. The structure of the triazacryptand was determined by X-ray diffraction (XRD) method. The anion binding properties of… (More)
DOI: 10.1021/ic301546v


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