A three-dimensional cyanide-bridged heterometallic coordination polymer: poly[[diacetonitrilediaqua[μ₂-3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine-κ⁴N¹,N⁶:N³,N⁴]tetra-μ-cyanido-tetracyanidodimanganese(II)molybdate(IV)] dihydrate].
@article{Xu2014ATC,
title={A three-dimensional cyanide-bridged heterometallic coordination polymer: poly[[diacetonitrilediaqua[μ₂-3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine-κ⁴N¹,N⁶:N³,N⁴]tetra-μ-cyanido-tetracyanidodimanganese(II)molybdate(IV)] dihydrate].},
author={Xiao-Juan Xu},
journal={Acta crystallographica. Section C, Structural chemistry},
year={2014},
volume={70 Pt 11},
pages={
1029-32
}
}A metal coordination polymer, {[Mn2Mo(CN)8(C12H8N6)(CH3CN)2(H2O)2]·2H2O}n, has been synthesized by the reaction of Mn(ClO4)2·6H2O with 3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine (bptz) and (Bu3N)3[Mo(CN)8] at room temperature. The polymer was characterized by IR spectroscopy, elemental analysis and X-ray diffraction, and the magnetic properties were also investigated. The X-ray diffraction analysis reveals that the compound is a new three-dimensional coordination polymer with a PtS-type network… CONTINUE READING