A three-dimensional cyanide-bridged heterometallic coordination polymer: poly[[diacetonitrilediaqua[μ₂-3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine-κ⁴N¹,N⁶:N³,N⁴]tetra-μ-cyanido-tetracyanidodimanganese(II)molybdate(IV)] dihydrate].

@article{Xu2014ATC,
  title={A three-dimensional cyanide-bridged heterometallic coordination polymer: poly[[diacetonitrilediaqua[μ₂-3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine-κ⁴N¹,N⁶:N³,N⁴]tetra-μ-cyanido-tetracyanidodimanganese(II)molybdate(IV)] dihydrate].},
  author={Xiao-Juan Xu},
  journal={Acta crystallographica. Section C, Structural chemistry},
  year={2014},
  volume={70 Pt 11},
  pages={
          1029-32
        }
}
A metal coordination polymer, {[Mn2Mo(CN)8(C12H8N6)(CH3CN)2(H2O)2]·2H2O}n, has been synthesized by the reaction of Mn(ClO4)2·6H2O with 3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine (bptz) and (Bu3N)3[Mo(CN)8] at room temperature. The polymer was characterized by IR spectroscopy, elemental analysis and X-ray diffraction, and the magnetic properties were also investigated. The X-ray diffraction analysis reveals that the compound is a new three-dimensional coordination polymer with a PtS-type network… CONTINUE READING

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