A three-coordinate and quadruply bonded Mo-Mo complex.

@article{Tsai2006ATA,
  title={A three-coordinate and quadruply bonded Mo-Mo complex.},
  author={Yi-Chou Tsai and Yang-Miin Lin and Jen-Shiang K. Yu and Jenn-Kang Hwang},
  journal={Journal of the American Chemical Society},
  year={2006},
  volume={128 43},
  pages={
          13980-1
        }
}
Reaction of MoCl3(THF)3 with [Me2Si{NLi(Dipp)}2]2 (Dipp = 2,6-i-PrC6H3) afforded a triply bonded dimolybdenum complex 1,2-Mo2Cl2[Me2Si(NDipp)2]2 1, spanned by two Me2Si[N(Dipp)]2 ligands, thus resulting in a syn conformation. The air- and moisture-sensitive compound 1 was characterized by NMR spectroscopic, elemental, and single-crystal X-ray crystallographic analysis. Reduction of 1 by Na/Hg yielded the quadruply bonded dimeric complex Mo2[Me2Si(NDipp)2]2 2, which was also characterized by the… Expand
31 Citations
Journey from Mo-Mo quadruple bonds to quintuple bonds.
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