A tetranuclear Cu(II)-based 2D aggregate with an unprecedented tetradentate mu(4)-N1,N3,N7,N9-adeninate nucleobase.

@article{Yang2009ATC,
  title={A tetranuclear Cu(II)-based 2D aggregate with an unprecedented tetradentate mu(4)-N1,N3,N7,N9-adeninate nucleobase.},
  author={En-Cui Yang and Hong-kun Zhao and Yan Feng and Xiao-Jun Zhao},
  journal={Inorganic chemistry},
  year={2009},
  volume={48 8},
  pages={3511-3}
}
A unique tetranuclear Cu(II)-based 2D aggregate containing 26-membered Cu(II)ade macrocycles, [Cu(4)(DMF)(6)(mu(4)-ade)(2)(mu(2)-Cl)(2)Cl(4)](n) (1; Hade = adenine, DMF = N,N-dimethylformamide), was isolated by the reaction of CuCl(2) and Hade in a mixed DMF-methanol medium and structurally characterized by X-ray crystallography, elemental analysis, Fourier… CONTINUE READING