A study on the interior microstructures of working Sn particle electrode of Li-ion batteries by in situ X-ray transmission microscopy

@article{Chao2010ASO,
  title={A study on the interior microstructures of working Sn particle electrode of Li-ion batteries by in situ X-ray transmission microscopy},
  author={Sung-Chieh Chao and Yu-Chan Yen and Yen-Fang Song and Yi-ming Chen and Hung-Chun Wu and Nae‐Lih Wu},
  journal={Electrochemistry Communications},
  year={2010},
  volume={12},
  pages={234-237}
}

Figures from this paper

In Situ Transmission X-ray Microscopy Study on Working SnO Anode Particle of Li-Ion Batteries
The evolution of the interior microstructures of SnO during electrochemical lithiation/de-lithiation has been visualized by in situ transmission X-ray microscopy (TXM), complemented by in situ X-ray
Study on Microstructural Deformation of Working Sn and SnSb Anode Particles for Li-Ion Batteries by in Situ Transmission X-ray Microscopy
Sn-containing compounds are potential high-capacity anode materials for Li-ion batteries. They, however, suffer from significant dimensional variations during electrochemical lithiation and
Characterization of battery anode materials by X-ray and electron-based imaging techniques
  • K. Dong
  • Physics, Materials Science
  • 2020
The internal microstructure of a silicon electrode in a lithium ion battery was visualized by operando synchrotron X-ray radioscopy during battery cycling. The silicon particles were found to change
In situ and Operando Tracking of Microstructure and Volume Evolution of Silicon Electrodes by using Synchrotron X-ray Imaging.
TLDR
The internal microstructure of a silicon electrode in a lithium ion battery was visualized by operando synchrotron X-ray radioscopy during battery cycling and an expansion prolongation phenomenon was discovered whereby some particles continue expanding even after switching the battery current direction and shrinkage would be expected.
In Situ TEM on the Reversibility of Nanosized Sn Anodes during the Electrochemical Reaction
Excellent reversibility is crucial for the storage capacity and the cycle life of anode materials in high-performance lithium ion batteries, which has not been observed in alloy-type materials such
In Situ TEM Experiments of Electrochemical Lithiation and Delithiation of Individual Nanostructures
Understanding the microscopic mechanisms of electrochemical reaction and material degradation is crucial for the rational design of high‐performance lithium ion batteries (LIBs). A novel nanobattery
Understanding Stabilization in Nanoporous Intermetallic Alloy Anodes for Li-Ion Batteries Using Operando Transmission X-ray Microscopy.
TLDR
Operando transmission X-ray microscopy showed that during cycling NP-SbSn expands by only 60% in area and then contracts back nearly to its original size with no physical disintegration, which should be useful for designing nanoscale structures in alloying anodes.
Microstructural evolution of tin nanoparticles during in situ sodium insertion and extraction.
TLDR
Excellent cyclability was also observed during the reversible sodiation/desodiation cycles, showing great potential of Sn nanoparticles as a robust electrode material for rechargeable batteries.
...
...

References

SHOWING 1-10 OF 25 REFERENCES
Electrochemical and In Situ X‐Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites
We report our electrochemical and in situ x-ray diffraction experiments on a variety of tin oxide based compounds; SnO, SnO 2 , Li 2 SnO 3 , and SnSiO 3 glass, as cathodes opposite lithium metal in a
Monitoring dynamics of electrode reactions in Li-ion batteries by in situ ESEM
This paper introduces a novel in situ method for monitoring electrode reactions in lithium-ion batteries parallel to the electrochemical experiment (in situ electrochemical environmental scanning
On the Aggregation of Tin in SnO Composite Glasses Caused by the Reversible Reaction with Lithium
We show that the reaction mechanism in Li/[SnO:(B 2 O 3 ) x :(P 2 O 5 ) y glass (0.1≤x,y≤0.5)], Li/[SnO: B 2 O 3 ) 0.5 :(P 2 O 5 ) 0.5 :(K 2 CO 3 ) 0.04 glass] and Li/SnO cells is common. During the
Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material
A high-capacity lithium-storage material in metal-oxide form has been synthesized that can replace the carbon-based lithium intercalation materials currently in extensive use as the negative
Dilatometric Investigations of Graphite Electrodes in Nonaqueous Lithium Battery Electrolytes
A relatively uncommon technique known as in situ electrochemical dilatometry can be used to record the macroscopic expansion (dilatation) and contraction of graphite samples during charge/discharge
Bonding Patterns in Intermetallic Compounds
Intermetallic phases have long been among the black sheep in the family of chemical compounds. Their chemical bonding has eluded description by the valence rules, which otherwise are extremely
F
OF THE DISCLOSURE A gas Spring for a drawing table which has a cylinder, a piston in the cylinder, and a piston rod projecting from the piston through one end wall of the cylinder, the other end wall
"J."
however (for it was the literal soul of the life of the Redeemer, John xv. io), is the peculiar token of fellowship with the Redeemer. That love to God (what is meant here is not God’s love to men)
...
...