A structurally diverse series of aluminum chloride alkoxides [Cl(x)Al(mu-OR)(y)](n) (R = (n)Bu, (c)Hex, Ph, 2,4-(t)Bu2C6H3).

Abstract

A diverse series of aluminum chloride alkoxides, [Cl(x)Al(mu-OR)(y)](n) (R = (n)Bu, (c)Hex, Ph, 2,4-(t)Bu(2)C(6)H(3)), was synthesized using the reactions of dichlorethylalane (EtAlCl(2)) with cyclohexanol ((c)HexOH), n-butanol ((n)BuOH), and phenols (PhOH and 2,4-(t)Bu(2)C(6)H(3)OH). Eight molecular products were isolated and structurally characterized… (More)
DOI: 10.1021/ic802251g

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