A stable single-site palladium catalyst for hydrogenations.

@article{Vil2015ASS,
  title={A stable single-site palladium catalyst for hydrogenations.},
  author={Gianvito Vil{\'e} and Davide Albani and Maarten Nachtegaal and Zupeng Chen and Dariya Dontsova and Markus Antonietti and N{\'u}ria L{\'o}pez and Javier P{\'e}rez-Ram{\'i}rez},
  journal={Angewandte Chemie},
  year={2015},
  volume={54 38},
  pages={11265-9}
}
We report the preparation and hydrogenation performance of a single-site palladium catalyst that was obtained by the anchoring of Pd atoms into the cavities of mesoporous polymeric graphitic carbon nitride. The characterization of the material confirmed the atomic dispersion of the palladium phase throughout the sample. The catalyst was applied for three-phase hydrogenations of alkynes and nitroarenes in a continuous-flow reactor, showing its high activity and product selectivity in comparison… CONTINUE READING
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