A spectroscopic and computational study of Al(III) complexes in cryolite melts: Effect of cation nature

@inproceedings{Nazmutdinov2013ASA,
  title={A spectroscopic and computational study of Al(III) complexes in cryolite melts: Effect of cation nature},
  author={Renat R. Nazmutdinov and Tamara T. Zinkicheva and Sergey Yu. Vassiliev and Dmitrii V. Glukhov and Galina A. Tsirlina and Michael M Probst},
  booktitle={Chemical physics},
  year={2013}
}
Lithium, sodium and potassium cryolite melts are probed by Raman spectroscopy in a wide range of the melt composition. The experimental data demonstrate a slight red shift of main peaks and a decrease of their half-widths in the row Li(+), Na(+), K(+). Quantum chemical modelling of the systems is performed at the density functional theory level. The ionic… CONTINUE READING