A room temperature reversible phase transition containing dielectric switching of a host-guest supramolecular metal-halide compound.

@article{Lu2017ART,
  title={A room temperature reversible phase transition containing dielectric switching of a host-guest supramolecular metal-halide compound.},
  author={Yang Lu and Xiu-Ni Hua and Weiqiang Liao and Ji-Xing Gao and Zi Yin},
  journal={Dalton transactions},
  year={2017},
  volume={46 38},
  pages={
          12760-12765
        }
}
Following our recent findings on dielectric materials, we synthesized a new host-guest supramolecular metal-halide compound, [(2-AMPD)(18-crown-6)]CuCl4 (1, 2-AMPD = 2-aminomethylpiperidinium). Systematic characterization techniques such as variable-temperature crystal structure analyses, differential scanning calorimetry (DSC) measurements, temperature-dependent dielectric measurements and powder X-ray diffraction (PXRD) measurements demonstrate that 1 undergoes a reversible phase transition… 
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7 Citations

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