A revisit to the retention mechanism of hydrophilic interaction liquid chromatography using model organic compounds.

@article{Karatapanis2011ART,
  title={A revisit to the retention mechanism of hydrophilic interaction liquid chromatography using model organic compounds.},
  author={Andreas E Karatapanis and Yiannis Ch Fiamegos and Constantine D Stalikas},
  journal={Journal of chromatography. A},
  year={2011},
  volume={1218 20},
  pages={2871-9}
}
In this work, a revisit to the retention mechanism of HILIC was attempted to point out critical factors that contribute to the chromatographic regime as well as to bring out subtle details of the relative contribution of partitioning and surface adsorption. In this vein, the retention behaviour of a set of water-soluble vitamins (WSVs) and toluene on three silica based columns was evaluated under varying chromatographic conditions. The data obtained were associated with the hydration degree of… CONTINUE READING
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