A polar tetrazolyl-carboxyl microporous Zn(II)-MOF: sorption and luminescent properties.


A Zn(II)-MOF [Zn(2)(tzba)(DMF)]·0.5DMF (1) (H(2)tzba = 4-(1H-tetrazol-5-yl) benzoic acid, DMF = N,N'-dimethylformamide) has been solvothermally synthesized and characterized. 1 is a three-dimensional (3D) microporous framework possessing an unusual multi-nodal (3,3,6)- or (4,4,4,4)-connected topological net. The small-sized pores, open metal sites, phenyl… (More)
DOI: 10.1039/c2dt31968c


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