A novel method of measuring the protonation of sulphoxides

@article{Quintily1971ANM,
  title={A novel method of measuring the protonation of sulphoxides},
  author={U. Quintily and Gianfranco Scorrano},
  journal={Journal of The Chemical Society D: Chemical Communications},
  year={1971},
  pages={260-261}
}
The amplitude of the shorter wavelength dichroic extremum of optically active phenyl alkyl sulphoxides depends on the degree of protonation of the SO group and may be used to evaluate their pKa. 
5 Citations
Conformation and absolute configuration of 2-naphthylalkylsulfoxides by combined use of dynamic NMR, ECD spectroscopy, DFT computations, and X-ray diffraction.
The E/Z conformer ratios of five 2-naphtylalkylsulfoxides were determined by means of dynamic NMR spectroscopy at very low temperatures and this information was used to predict, by means of DFT
Thiol Additions To Dissymmetrical 1,4-Diary Sulfonyl-2-Butynes Regioselectivity And Stereoselectivity
Abstract Regioselectivity is restored in the addition of thiols to 1,4-diarylsulfonyl-2-butynes based on differing electron-demands of the substituents on the aromatic rings attached to the butynyl
Sulfoxides and Sulfilimines
Sulfoxides are formed by partial oxidation of sulfides, which upon further oxidation are converted to sulfones, and hence may be considered as a very stable intermediate in the oxidation process.