A novel metabolic pathway for degradation of 4-nonylphenol environmental contaminants by Sphingomonas xenophaga Bayram: ipso-hydroxylation and intramolecular rearrangement.

@article{Gabriel2005ANM,
  title={A novel metabolic pathway for degradation of 4-nonylphenol environmental contaminants by Sphingomonas xenophaga Bayram: ipso-hydroxylation and intramolecular rearrangement.},
  author={Fr{\'e}d{\'e}ric L. P. Gabriel and Andy Heidlberger and Daniel Rentsch and Walter Giger and Klaus Guenther and Hans-Peter E Kohler},
  journal={The Journal of biological chemistry},
  year={2005},
  volume={280 16},
  pages={
          15526-33
        }
}
  • Frédéric L. P. Gabriel, Andy Heidlberger, +3 authors Hans-Peter E Kohler
  • Published in
    The Journal of biological…
    2005
  • Chemistry, Medicine
  • Several nonylphenol isomers with alpha-quaternary carbon atoms serve as growth substrates for Sphingomonas xenophaga Bayram, whereas isomers containing hydrogen atoms at the alpha-carbon do not. Three metabolites of 4-(1-methyloctyl)-phenol were isolated in mg quantities from cultures of strain Bayram supplemented with the growth substrate isomer 4-(1-ethyl-1,4-dimethyl-pentyl)-phenol. They were unequivocally identified as 4-hydroxy-4-(1-methyl-octyl)-cyclohexa-2,5-dienone, 4-hydroxy-4-(1… CONTINUE READING

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