A novel family of triangular CoII2LnIII and CoII2YIII clusters by the employment of Di-2-Pyridyl ketone

@article{Efthymiou2019ANF,
  title={A novel family of triangular CoII2LnIII and CoII2YIII clusters by the employment of Di-2-Pyridyl ketone},
  author={Constantinos G. Efthymiou and {\'A}ine N{\'i} Fhuar{\'a}in and J. Mayans and A. Tasiopoulos and S. Perlepes and Constantina Papatriantafyllopoulou},
  journal={Magnetochemistry},
  year={2019},
  volume={5},
  pages={35}
}
The synthesis, structural characterization and magnetic study of novel CoII/4f and CoII/YIII clusters are described. In particular, the initial employment of di-2-pyridyl ketone, (py)2CO, in mixed metal Co/4f chemistry, provided access to four triangular clusters, [CoII2MIII{(py)2C(OEt)(O)}4(NO3)(H2O)]2[M(NO3)5](ClO4)2 (M = Gd, 1; Dy, 2; Tb, 3; Y, 4), where (py)2C(OEt)(O)− is the monoanion of the hemiketal form of (py)2CO. Clusters 1–4 are the first reported Co/4f (1–3) and Co/Y (4) species… Expand
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