A novel asymmetric hydroarsination reaction promoted by a chiral organopalladium complex.

Abstract

The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di-mu-chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reaction promoter.

Cite this paper

@article{Bungabong2007ANA, title={A novel asymmetric hydroarsination reaction promoted by a chiral organopalladium complex.}, author={Maricar L Bungabong and Kien Wee Tan and Yongxin Li and Selvasothi V Selvaratnam and Krishna Gopal Dongol and Pak-Hing Leung}, journal={Inorganic chemistry}, year={2007}, volume={46 11}, pages={4733-6} }