A novel S-adenosyl-L-methionine:arsenic(III) methyltransferase from rat liver cytosol.

@article{Lin2002ANS,
  title={A novel S-adenosyl-L-methionine:arsenic(III) methyltransferase from rat liver cytosol.},
  author={Shan Xi Lin and Qing Chun Shi and Francis Nix and Miroslav Stỳblo and Melinda A Beck and Karen M Herbin-Davis and Larry L. Hall and Josef B. Simeonsson and David J Thomas},
  journal={The Journal of biological chemistry},
  year={2002},
  volume={277 13},
  pages={
          10795-803
        }
}
S-Adenosyl-l-methionine (AdoMet):arsenic(III) methyltransferase, purified from liver cytosol of adult male Fischer 344 rats, catalyzes transfer of a methyl group from AdoMet to trivalent arsenicals producing methylated and dimethylated arsenicals. The kinetics of production of methylated arsenicals in reaction mixtures containing enzyme, AdoMet, dithiothreitol, glutathione (GSH), and arsenite are consistent with a scheme in which monomethylated arsenical produced from arsenite is the substrate… CONTINUE READING

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