A non-oxidative approach toward chemically and electrochemically functionalizing Si(111).

Abstract

A general method for the non-oxidative functionalization of single-crystal silicon(111) surfaces is described. The silicon surface is fully acetylenylated using two-step chlorination/alkylation chemistry. A benzoquinone-masked primary amine is attached to this surface via Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition ("click" chemistry). The… (More)
DOI: 10.1021/ja062012b

Topics

7 Figures and Tables

Cite this paper

@article{Rohde2006ANA, title={A non-oxidative approach toward chemically and electrochemically functionalizing Si(111).}, author={Rosemary D. Rohde and Heather D. Agnew and Woon-Seok Yeo and Ryan C Bailey and James R. Heath}, journal={Journal of the American Chemical Society}, year={2006}, volume={128 29}, pages={9518-25} }