A new avenue for the preparation of organoboron compounds via nickel catalysis

  title={A new avenue for the preparation of organoboron compounds via nickel catalysis},
  author={Samir Manna and Kanak Kanti Das and Soumilee Nandy and Debasish Aich and Swagata Paul and Santanu Panda},
  journal={Coordination Chemistry Reviews},
3 Citations
A Unified Synthetic Strategy to Introduce Heteroatoms via Electrochemical Functionalization of Alkyl Organoboron Reagents.
Based on systematic electrochemical analysis, an integrated synthetic platform of C(sp3)-based organoboron compounds was established for the introduction of heteroatoms. The electrochemically
Development of Methods to the Synthesis of β‐Boryl Acyls, Imines and Nitriles
Organoboron compounds are highly important and versatile synthetic intermediates for the preparation of a wide range of organic molecules. Organoboron compounds have drawn significant attention among


Transition metal catalyzed asymmetric multicomponent reactions of unsaturated compounds using organoboron reagents.
This review will discuss the merits and scope of multicomponent strategies based on their difference in the reaction mechanism and transition metals involved.
Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates.
A new and efficient nickel-catalyzed decarbonylative borylation reaction of carboxylic acid esters with bis(pinacolato)-diboron has been developed. This transformation allows access to structurally
Migratory Arylboration of Unactivated Alkenes Enabled by Nickel Catalysis.
An unprecedented arylboration of unactivated terminal alkenes, featuring 1,n-regioselectivity, has been achieved by nickel catalysis, and preliminary mechanistic studies indicate that although the metal migration favors the α-position of boron, selective and decisive bond formation is favored at the benzylic position.
Ni-Catalyzed Arylboration of Unactivated Alkenes: Scope and Mechanistic Studies.
The reaction is notable in that it converts highly substituted alkenes, aryl bromides, and diboron reagents to products that contain a quaternary carbon and a synthetically versatile carbon-boron bond with control of stereoselectivities and regioselectivity.
Transition-Metal-Catalyzed 1,2-Carboboration of Alkenes: Strategies, Mechanisms, and Stereocontrol.
This review summarizes advances in 1,2-Carboboration, with a special focus on the catalytic cycles involved in different metal-catalyzed carboboration reactions, as well as the regio- and stereochemical consequences of the underlying mechanisms.
A phenalenyl-based nickel catalyst for the hydroboration of olefins under ambient conditions.
The mechanistic investigations revealed that the alkene hydroboration reaction takes place through a single electron transfer from the phenalenyl ligand backbone leading to the cleavage of the B-H bond.
Catalytic bismetallative multicomponent coupling reactions: scope, applications, and mechanisms.
This review highlights key developments of transition-metal catalyzed bismetallative reactions involving multiple π components and will highlight the scope, synthetic applications, and proposed mechanistic pathways of this process.
Photoinduced Borylation for the Synthesis of Organoboron Compounds.
This Focus Review summarizes research on photoinduced borylations, especially emphasizing recent developments and trends and focuses on reaction mechanisms involving single-electron transfer, triplet-energy transfer, and other radical processes.