A luminescent mixed-lanthanide metal-organic framework thermometer.

@article{Cui2012ALM,
  title={A luminescent mixed-lanthanide metal-organic framework thermometer.},
  author={Yuanjing Cui and Hui Xu and Yanfeng Yue and Zhiyong Guo and Jiancan Yu and Zhenxia Chen and Junkuo Gao and Yu Yang and Guodong Qian and Banglin Chen},
  journal={Journal of the American Chemical Society},
  year={2012},
  volume={134 9},
  pages={
          3979-82
        }
}
A luminescent mixed lanthanide metal-organic framework approach has been realized to explore luminescent thermometers. The targeted self-referencing luminescent thermometer Eu(0.0069)Tb(0.9931)-DMBDC (DMBDC = 2, 5-dimethoxy-1, 4-benzenedicarboxylate) based on two emissions of Tb(3+) at 545 nm and Eu(3+) at 613 nm is not only more robust, reliable, and instantaneous but also has higher sensitivity than the parent MOF Tb-DMBDC based on one emission at a wide range from 10 to 300 K. 

Figures from this paper

Ratiometric Thermometer Based on a Lanthanoid Coordination Polymer
The new luminescent lanthanum-based coordination polymer LaHL, ({[La(HL)(H2O)2]·H2O}n, H4L = 5-hydroxy-1,2,4-benzenetricarboxylic acid) has been synthesized by hydrothermal methods. By the addition
Luminescent lanthanide–organic polyrotaxane framework as a turn-off sensor for nitrobenzene and Fe3+
Three isomorphous lanthanide–organic polyrotaxane frameworks [Ln(mtpc)1.5(DMA)(H2O)]·2H2O [Ln = Tb (1); Dy (2); Er (3)] were assembled and characterized. In 1, the mtpc ligand transfer absorbed
A highly sensitive mixed lanthanide metal-organic framework self-calibrated luminescent thermometer.
A new mixed lanthanide metal-organic framework thermometer Tb0.9Eu0.1PIA with the significantly high sensitivity of 3.53% per K has been realized by making use of an organic ligand,
Lanthanide Complex Hybrid System for Fluorescent Sensing as Thermometer
A mixed lanthanide complex was synthesized hydrothermally with two kinds of organic ligands, adenine and biphenyl-4,4′-dicarboxylic acid, and is formulated as Ad/Tb0.999Eu0.001/BPDC (Ad = adeninate,
A Ratiometric Luminescent Thermometer Co-doped with Lanthanide and Transition Metals.
Herein, we report the fabrication of a sensitive ratiometric and colorimetric luminescent thermometer with a wide operating-temperature range, from cryogenic temperatures up to high temperatures,
Mixed-Lanthanoid Metal-Organic Framework for Ratiometric Cryogenic Temperature Sensing.
A ratiometric thermometer based on a mixed-metal Ln(III) metal-organic framework is reported that has good sensitivity in a wide temperature range from 4 to 290 K and a quantum yield of 22% at room
Mixed-Lanthanide Metal–Organic Frameworks with Tunable Color and White Light Emission
Three isostructural lanthanide metal–organic frameworks (Ln-MOFs, Ln = Eu3+, Tb3+, Dy3+) containing P-terphenyl-2,2″,4,4″-tetracarboxylate ligand (H4L) with red, green, and blue luminescence were
A dual-emitting Cu6-Cu2-Cu6 cluster as a self-calibrated, wide-range luminescent molecular thermometer.
TLDR
The high thermal stability, well-resolved blue/red dual emissions and two-way luminescent thermochromism warrant its self-calibrated temperature sensing ability, covering a wide range (120-450 K).
A Bimetallic Lanthanide Metal–Organic Material as a Self‐Calibrating Color‐Gradient Luminescent Sensor
TLDR
A new bimetallic lanthanide metal-organic framework exhibits high-sensitivity luminescent sensing of mixtures of organic compounds and can work over a large range of volume ratios.
...
1
2
3
4
5
...

References

SHOWING 1-10 OF 36 REFERENCES
Luminescent metal-organic frameworks.
TLDR
This critical review discusses the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules.
Zinc-adeninate metal-organic framework for aqueous encapsulation and sensitization of near-infrared and visible emitting lanthanide cations.
TLDR
It is demonstrated that bio-MOF-1 encapsulates and sensitizes visible and near-infrared emitting lanthanide cations in aqueous solution.
Near-infrared luminescent lanthanide MOF barcodes.
We demonstrate the conceptual advantage of using metal-organic frameworks (MOFs) for the creation of a polymetallic material that contains several different near-IR-emitting lanthanide cations and
Temperature-dependent luminescent properties of Eu–Tb complexes synthesized in situ in gel glass
The chelates of europium and terbium with hexafluoroacetylacetone (HFA) and triphenylphoshine oxide (TPPO), Eu∕Tb(HFA)3(TPPO)2, have been synthesized in situ in gel glasses with various
Luminescent multifunctional lanthanides-based metal-organic frameworks.
TLDR
The potential of LnMOFs as multifunctional systems, which combine light emission with properties such as microporosity, magnetism, chirality, molecule and ion sensing, catalysis and activity as multimodal imaging contrast agents, is discussed.
Temperature-Sensitive Luminescent Nanoparticles and Films Based on a Terbium (III) Complex Probe
The terbium-tris[(2-hydroxy-benzoyl)-2-aminoethyl]amine complex (Tb-THBA) with its high color purity, long luminescence lifetime, and high quantum yield has been found to be a viable indicator for
Progress on lanthanide-based organic-inorganic hybrid phosphors.
TLDR
This tutorial review offers a general overview of the myriad of advanced Ln(3+)-based organic-inorganic hybrid materials recently synthesised, which may be viewed as a major innovation in areas of phosphors, lighting, integrated optics and optical telecommunications, solar cells, and biomedicine.
A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide
1H-Imidazo[4,5-f][1,10]phenanthroline (Hip) can be deprotonated to bridge Zn(II) ions, giving a flexible porous metal azolate framework [Zn7(ip)12](OH)2 (MAF-34) which shows not only drastic
A guest-responsive fluorescent 3D microporous metal-organic framework derived from a long-lifetime pyrene core.
The carboxylate ligand 1,3,6,8-tetrakis(p-benzoic acid)pyrene (TBAPy)-based on the strongly fluorescent long-lifetime pyrene core-affords a permanently microporous fluorescent metal-organic
...
1
2
3
4
...