A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition.

@article{Sheu2012ALP,
  title={A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition.},
  author={Chou-Fu Sheu and Che-Hsiu Shih and Kunihisa Sugimoto and Bing-Ming Cheng and Masaki Takata and Yu Wang},
  journal={Chemical communications},
  year={2012},
  volume={48 46},
  pages={
          5715-7
        }
}
In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe(II)(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K. 
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The spin crossover salt can be reversibly dehydrated to afford 1 , a material that also exhibits spin crossover coupled to H-bond isomerization, leading to strong kinetic effects in the thermomagnetic properties.
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Structural studies into the spin crossover behaviour of Fe(abpt)2(NCS)2 polymorphs B and D
Crystallographic analysis of the spin-crossover behaviour of [Fe(abpt)2(NCS)2], polymorph B and D, is presented focusing particularly on the high pressure structures.
Light-Induced Spin-crossover
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The spin crossover behaviour of [Fe(abpt)2(NCSe)2] (abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) polymorph A has been examined using single crystal X-ray diffraction and variable temperature…
Photochromism and Photomagnetism Induced by Structural Disorder of a Crystalline Spin-Crossover FeII Complex
Photochromic and photoswitchable magnetic (photomagnetic) properties of spin-crossover (SCO) metal complexes in the solid state were observed almost at cryogenic temperature. Here we present a new…
Structural and spectroscopic characterisation of the spin crossover in [Fe(abpt)(2)(NCS)(2)] polymorph A
A crystallographic and solid state spectroscopic study of the spin crossover behaviour of [Fe(abpt)2(NCS)2] (abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) polymorph A is reported. Structural…
Thermoanalytical study of linkage isomerism in coordination compounds. Part III: A DSC study on the effect of counterion on the solid state isomerization of nitro and nitrito linkage isomers of pentaamminecobalt(III) complexes
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