A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes.

@article{Mantel2003AHA,
  title={A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes.},
  author={Claire Mantel and Alia K Hassan and Jacques P{\'e}caut and Alain Deronzier and Marie‐No{\"e}lle Collomb and Carole Duboc-Toia},
  journal={Journal of the American Chemical Society},
  year={2003},
  volume={125 40},
  pages={
          12337-44
        }
}
The isolation, structural characterization and electronic properties of three new six-coordinated Mn(III) complexes, [Mn(bpea)(F)(3)] (1), [Mn(bpea)(N(3))(3)] (2), and [Mn(terpy)(F)(3)] (3) are reported (bpea = N,N-bis(2-pyridylmethyl)-ethylamine; terpy = 2,2':6',2' '-terpyridine). As for [Mn(terpy)(N(3))(3)] (4) (previously described by Limburg J.; Vrettos J. S.; Crabtree R. H.; Brudvig G. W.; de Paula J. C.; Hassan A.; Barra A-L.; Duboc-Toia C.; Collomb M-N. Inorg. Chem. 2001, 40, 1698), all… 
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Definition of magneto-structural correlations for the MnII ion.
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