• DOI:10.1039/c7nr00911a
• Corpus ID: 206097724

A gigantically increased ratio of electrical to thermal conductivity and synergistically enhanced thermoelectric properties in interface-controlled TiO2-RGO nanocomposites.

@article{Nam2017AGI,
  title={A gigantically increased ratio of electrical to thermal conductivity and synergistically enhanced thermoelectric properties in interface-controlled TiO2-RGO nanocomposites.},
  author={Woo Hyun Nam and Young Soo Lim and Woochul Kim and Hyeon Kook Seo and Kyun Seong Dae and Soonil Lee and Won Seon Seo and Jeong Yong Lee},
  journal={Nanoscale},
  year={2017},
  volume={9 23},
  pages={
          7830-7838
        }
}

• W. H. Nam, Y. Lim, +5 authors Jeong Yong Lee
• Published 14 June 2017
• Materials Science, Engineering
• Nanoscale

We report synergistically enhanced thermoelectric properties through the independently controlled charge and thermal transport properties in a TiO2-reduced graphene oxide (RGO) nanocomposite. By the consolidation of TiO2-RGO hybrid powder using spark plasma sintering, we prepared an interface-controlled TiO2-RGO nanocomposite where its grain boundaries are covered with the RGO network. Both the enhancement in electrical conductivity and the reduction in thermal conductivity were simultaneously achieved thanks to the beneficial effects of the RGO network, and detailed mechanisms are discussed. This led to the gigantic increase in the ratio of electrical to thermal conductivity by six orders of magnitude and also the synergistic enhancement in the thermoelectric figure of merit by two orders. Our results present a strategy for the realization of 'phonon-glass electron-crystals' through interface control using graphene in graphene hybrid thermoelectric materials.