A functional model for the Rieske center: full characterization of a biomimetic N-ligated [2Fe-2S] cluster in different protonation states.


Give and take both: A bis(benzimidazolate)-capped biomimetic [2Fe-2S] cluster has been characterized in different protonation states, both in the diferric and mixed-valent forms. Protonation does not lead to structural changes of the [2Fe-2S] core, but facilitates its reduction and causes pronounced valence localization in the mixed-valent state. Concerted… (More)
DOI: 10.1002/chem.201301760


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