A facile synthesis of trinaphtho[3.3.3]propellane and its π-extension and the formation of a two-dimensional honeycomb molecular assembly.

Abstract

The multi-gram-scale synthesis of trinaphtho[3.3.3]propellane (TNP) and its π-extension were achieved. X-ray crystallographic analysis revealed that charge transfer complexes of the π-extended TNP with F4-TCNQ form a two-dimensional honeycomb lattice. 
DOI: 10.1039/c4cc09883h

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