A decatungstate-based ionic liquid exhibiting a very low dielectric constant suitable for acting as a solvent and a catalyst for the oxidation of organic substrates

@article{Martinetto2021ADI,
  title={A decatungstate-based ionic liquid exhibiting a very low dielectric constant suitable for acting as a solvent and a catalyst for the oxidation of organic substrates},
  author={Yohan Martinetto and Bruce P{\'e}got and Catherine Roch-Marchal and Mohamed Haouas and Betty Cottyn-Boitte and Franck Camerel and Jelena Jefti{\'c} and Denis Morineau and Emmanuel Magnier and S{\'e}bastien Floquet},
  journal={New Journal of Chemistry},
  year={2021}
}
The use of a POM-based ionic liquid both as an efficient solvent and as a catalyst for the oxidation of organic substrates. 

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References

SHOWING 1-10 OF 32 REFERENCES

Tetraalkylphosphonium polyoxometalates: electroactive, "task-specific" ionic liquids.

The pairing of selected polyoxometalate (POM) anions with appropriate tetraalkylphosphonium cations is shown to yield an original family of ionic liquids, among them an ambient-temperature "liquid

Terpyridine-functionalized imidazolium ionic liquids.

This paper reports the synthesis and the physical characterization of a new family of chelating ionic liquids carrying a terpyridine fragment suitable for metal extraction.

Oxidation of styrene and cyclohexene under microwave conditions

The coupling of microwave energy with solvent-free phase-transfer catalysis was studied for the oxidation of cyclohexene and styrene. The former Noyori oxidation system (Science, 1998, 281, 1646) was

Microwave-assisted oxidation of alcohols by hydrogen peroxide catalysed by tetrabutylammonium decatungstate

This work deals with catalytic activity of tetrabutylammonium decatungstate(VI) in the oxidation of selected alcohols with hydrogen peroxide as an oxidant using 1,2-dichloroethane/water or

Quaternary ammonium decatungstate catalyst for oxidation of alcohols

This work describes the use of hydrogen peroxide as oxidant for the selective oxidation of some alcohols in the presence of hexadecyl trimethyl ammonium decatungstate catalyst under simple reaction

Designing Functional Polyoxometalate-Based Ionic Liquid Crystals and Ionic Liquids

Polyoxometalate (POM) compounds constitute a wide family rich of more than several thousand inorganic compounds which can be finely tuned at the molecular level. Considering their high diversities in

Catalytic oxidation of olefins and alcohols with hydrogen peroxide in a two-phase system giving mono- and dicarboxylic acids

The present study considered the influence of various factors on the catalytic activity of systems based on a combination of tetrakis(oxodiperoxotungsto)phosphate(3−) with quaternary ammonium

Clean synthesis of adipic acid by direct oxidation of cyclohexene with H2O2 over peroxytungstate–organic complex catalysts

Directly catalytic oxidation of cyclohexene to adipic acid with hydrogen peroxide over environmentally benign peroxytungstate–organic complex catalysts is performed with excellent yields and

Efficient Epoxidation of Olefins with ≥99% Selectivity and Use of Hydrogen Peroxide

The effectiveness of this catalyst is evidenced by ≥99% selectivity to epoxide, ≥ 99% efficiency of H2O2 utilization, high stereospecificity, and easy recovery of the catalyst from the homogeneous reaction mixture.