A crab claw shaped molecular receptor for selective recognition of picric acid: supramolecular self-assembly mediated aggregation induced emission and color change

@article{Pitchaimani2017ACC,
  title={A crab claw shaped molecular receptor for selective recognition of picric acid: supramolecular self-assembly mediated aggregation induced emission and color change},
  author={Jayaraman Pitchaimani and Anup K. Kundu and Subramanian Vedhanarayanan Karthikeyan and Savarimuthu Philip Anthony and Dohyun Moon and Vedichi Madhu},
  journal={CrystEngComm},
  year={2017},
  volume={19},
  pages={3557-3561}
}
2,6-Pyridine bis(iminoantipyrine) (PyBAP), a crab claw shaped open neutral molecular receptor with multiple non-covalent sites, showed selective recognition of picric acid (PA) through supramolecular interactions that lead to an intermolecular charge transfer induced naked-eye detectable color change both in solution as well as in the solid state and rare turn-on solid state fluorescence. The selective host–guest formation of PyBAP–PA has been confirmed using 1H-NMR, single crystal structural… Expand
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