A convenient synthesis and a NMR study of the diammoniate of diborane.


DADB synthesis: The diammoniate of diborane (DADB) was synthesized in a new metathesis reaction between the diammoniate of monochloroborane and potassium borohydride in liquid ammonia. (1)H and (11)B NMR spectra of DADB are reported. The stability in THF was examined by variable-temperature (11)B NMR spectroscopy. 
DOI: 10.1002/chem.201103693


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