A convenient MnIII starting material for the synthesis of homo- and heterometallic manganese carboxylate clusters: Mn9 and Mn10−xFex complexes

  title={A convenient MnIII starting material for the synthesis of homo- and heterometallic manganese carboxylate clusters: Mn9 and Mn10−xFex complexes},
  author={C. Lampropoulos and T. Stamatatos and K. Abboud and G. Christou},
Abstract The use of a convenient source of MnIII ions, namely the [Mn(OR)(O2CR′)2]n (R = H, Me, and R′ = Me, But) family of 1-D coordination polymers, afforded two new enneanuclear and decanuclear molecular clusters, homometallic [Mn9O7(O2CBut)13(MeCN)2] (3) and heterometallic [Mn10−xFex(OMe)20(O2CMe)10] (x 

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