A consistent calculation of the chemical potential for dense simple fluids.

  • J. M. Bomont
  • Published 2006 in The Journal of chemical physics

Abstract

A general method to calculate the excess chemical potential betamuex, that is based on the Kirkwood coupling parameter's dependence of the correlation functions, is presented. The expression for the one particle bridge function B(1)r is derived for simple fluids with spherical interactions. Only the knowledge of the bridge function B(2)r is required. The… (More)

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