A complementary guest induced morphology transition in a two-component multiple H-bonding self-assembly.

Abstract

An oligo(p-phenylenevinylene) (OPV) dimer, whose OPV units are capped on their end by monotopic melamine hydrogen-bonding units, self-assembles in methylcyclohexane to form flexible fibrous nanostructures, which are transformed into rigid nanostrips upon adding ditopic cyanurates and reconverted to nanofibers upon adding a m-xylylene-linked bismelamine. 
DOI: 10.1039/b921959e

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