A common and versatile synthetic route to (-) and (+) pentenomycin I, (+) halopentenomycin I and dehydropentenomycin.

Abstract

A versatile and stereoselective total synthesis of (+) and (-) pentenomycin I, (+) halopentenomycins I and dehydropentenomycin from a common chiral polyhydroxylated cyclopentene through oxidation and protection/deprotection has been described. Stereoselective hydroxymethylation, stereoselective Grignard reaction and ring closing metathesis are the key… (More)
DOI: 10.1016/j.carres.2015.08.003

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Cite this paper

@article{Das2015ACA, title={A common and versatile synthetic route to (-) and (+) pentenomycin I, (+) halopentenomycin I and dehydropentenomycin.}, author={Sulagna Das and Amarendra Panda and Shantanu Pal}, journal={Carbohydrate research}, year={2015}, volume={416}, pages={24-31} }