A chiral probe for the detection of Cu(II) by UV, CD and emission spectroscopies.

@article{Moletti2007ACP,
  title={A chiral probe for the detection of Cu(II) by UV, CD and emission spectroscopies.},
  author={Alberto Moletti and Carmine Coluccini and Dario Pasini and Angelo Taglietti},
  journal={Dalton transactions},
  year={2007},
  volume={16},
  pages={1588-92}
}
The synthesis and characterization of the new chiral ligand 2, based on a BINOL-tren (tren = tris(2-aminoethyl)amine) conjugate, in enantiomerically pure form, are reported. UV-Vis spectrophotometric and spectrofluorimetric studies at variable pH show that the incorporation of a phenolic functionality in close proximity to the polyamino fragment of the molecule causes a dramatic variation of the acid-base and coordination properties of the molecule; the major role of this functionality in… CONTINUE READING

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