A bracket approach to improve the stability and gas sorption performance of a metal-organic framework via in situ incorporating the size-matching molecular building blocks.


Incorporating the in situ formed size-matching molecular building blocks (MBBs) into the open channels will remarkably improve the robustness and gas sorption performance of an evacuated metal-organic framework. As a result, such MBBs can transfer the open metal sites from the framework walls to the channel centers and separate the large channels into… (More)
DOI: 10.1039/c6cc02359b


4 Figures and Tables