A Rh-catalyzed regio- and stereoselective route to enamides: benzamides as assembling reagents.

@article{Lee2014ARR,
  title={A Rh-catalyzed regio- and stereoselective route to enamides: benzamides as assembling reagents.},
  author={Dong Jin Lee and Jinhwan Shin and Eun Jeong Yoo},
  journal={Chemical communications},
  year={2014},
  volume={50 50},
  pages={6620-2}
}
A new protocol for the synthesis of fully substituted enaminones has been achieved using a diverse range of benzamides and 1-sulfonyl-1,2,3-triazoles. Selective removal of the β-amino moiety of the obtained α-amido-enaminones to form Z-enamides was also demonstrated thus improving the synthetic value of benzamides for structural diversities in a minimum… CONTINUE READING

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