A Representative Synthetic Route for C5 Angucycline Glycosides: Studies Directed toward the Total Synthesis of Mayamycin.

@article{Chakraborty2018ARS,
  title={A Representative Synthetic Route for C5 Angucycline Glycosides: Studies Directed toward the Total Synthesis of Mayamycin.},
  author={Soumen Chakraborty and Dipakranjan Mal},
  journal={The Journal of organic chemistry},
  year={2018},
  volume={83 3},
  pages={
          1328-1339
        }
}
This study discloses an efficient synthetic route for the regiospecific construction of a C5 glycoside angucycline representative of mayamycin. The key steps are intramolecular aldol condensation and Hauser annulation, and the key precursor for the aldol reaction is accessible through utilization of α-lithiation of a vinyl ether. 
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