A Novel Family of Triangular CoII2LnIII and CoII2YIII Clusters by the Employment of Di-2-Pyridyl Ketone

@inproceedings{Efthymiou2019ANF,
  title={A Novel Family of Triangular CoII2LnIII and CoII2YIII Clusters by the Employment of Di-2-Pyridyl Ketone},
  author={Constantinos G. Efthymiou and {\'A}ine N{\'i} Fhuar{\'a}in and J{\'u}lia Mayans and Anastasios J Tasiopoulos and Spyros P Perlepes and Constantina Papatriantafyllopoulou},
  year={2019}
}
The synthesis, structural characterization and magnetic study of novel CoII/4f and CoII/YIII clusters are described. In particular, the initial employment of di-2-pyridyl ketone, (py)2CO, in mixed metal Co/4f chemistry, provided access to four triangular clusters, [CoII2MIII{(py)2C(OEt)(O)}4(NO3)(H2O)]2[M(NO3)5](ClO4)2 (M = Gd, 1; Dy, 2; Tb, 3; Y, 4), where (py)2C(OEt)(O)− is the monoanion of the hemiketal form of (py)2CO. Clusters 1–4 are the first reported Co/4f (1–3) and Co/Y (4) species… CONTINUE READING
1
Twitter Mention