A New Protocol for the Synthesis of New Thioaryl-Porphyrins Derived from 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin: Photophysical Evaluation and DNA-Binding Interactive Studies

@inproceedings{Foletto2018ANP,
  title={A New Protocol for the Synthesis of New Thioaryl-Porphyrins Derived from 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin: Photophysical Evaluation and DNA-Binding Interactive Studies},
  author={Patr{\'i}cia Foletto and Fabiula Correa and Luciano do Amaral Dornelles and Bernardo A Iglesias and Carolina H da Silveira and Pablo A Nogara and Jo{\~a}o B T da Rocha and Maria Amparo F Faustino and Oscar E D Rodrigues},
  booktitle={Molecules},
  year={2018}
}
A new protocol for the preparation of thioaryl-porphyrins is described. The compounds were prepared from different disulfides employing NaBH₄ as a reducing agent. The methodology allowed the preparation of four different thioaryl-porphyrins in very-good to excellent yields under soft conditions, such as short reaction times and smooth heating. Additionally, the photophysical properties of new compounds were determined and experimental and theoretical DNA interactions were assessed. 

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