A Cationic Coordination Polymer and Its Orange II Anion-Exchanged Products: Isolation, Structural Characterization, Photocurrent Responses, and Dielectric Properties.

@article{Liu2017ACC,
  title={A Cationic Coordination Polymer and Its Orange II Anion-Exchanged Products: Isolation, Structural Characterization, Photocurrent Responses, and Dielectric Properties.},
  author={Dan Liu and Fei-Fan Lang and Xuan Zhou and Zhi-gang Ren and David James Young and Jianping Lang},
  journal={Inorganic chemistry},
  year={2017},
  volume={56 20},
  pages={12542-12550}
}
Solvothermal reactions of AgNO3 with N1,N4-bis(5-fluoropyridin-3-yl)succinamide (bfps) in MeCN afforded the one-dimensional cationic coordination polymer {[Ag(bfps)]NO3}n (1). Upon treatment of 1 with the anionic azo dye orange II (NaOII) in aqueous solution, the NO3- anions of 1 could be gradually exchanged by the OII- anions via an anion-exchange process. The resulting OII anion-exchanged products {[Ag(bfps)](NO3)0.85(OII)0.15}n (2) and {[Ag(bfps)](NO3)0.1(OII)0.9}n (3) were formed by… CONTINUE READING