A 1H‐NMR thermometer suitable for cryoprobes

@article{Findeisen2007A1T,
  title={A 1H‐NMR thermometer suitable for cryoprobes},
  author={M. Findeisen and T. Brand and S. Berger},
  journal={Magnetic Resonance in Chemistry},
  year={2007},
  volume={45}
}
Most established NMR thermometers rely on temperature‐dependent chemical shift differences measured from samples that are either neat or concentrated solutions (e.g. ethylene glycol, methanol). These are unsuitable for modern cryoprobes on account of strong radiation damping resulting from the high Q of the probe. Using perdeuterated methanol, we established a relationship between the chemical shift difference and temperature, and we show that this relationship is well fitted by a quadratic… Expand
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  • 5
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  • 2
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5
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References

SHOWING 1-10 OF 12 REFERENCES
Temperature accuracy and temperature gradients in solution-state NMR spectrometers.
  • 18
  • PDF
Sizable concentration-dependent frequency shifts in solution NMR using sensitive probes.
  • 33
  • PDF
Standardization of chemical shifts of TMS and solvent signals in NMR solvents
  • R. Hoffman
  • Chemistry, Medicine
  • Magnetic resonance in chemistry : MRC
  • 2006
  • 80
  • PDF
Temperature measurements using nuclear magnetic resonance
  • 18
  • Highly Influential
Temperature imaging by 1H NMR and suppression of convection in NMR probes
  • Hedin, Furó
  • Chemistry, Medicine
  • Journal of magnetic resonance
  • 1998
  • 44
A simple multinuclear NMR thermometer
  • 320
...
1
2
...