6-(3,5-Dimethyl-1H-pyrazol-1-yl)-2,2'-bipyridine as ligand for actinide(III)/lanthanide(III) separation.

@article{Girnt2010635Dimethyl1Hpyrazol1yl22bipyridineA,
  title={6-(3,5-Dimethyl-1H-pyrazol-1-yl)-2,2'-bipyridine as ligand for actinide(III)/lanthanide(III) separation.},
  author={Denise Girnt and Peter W Roesky and Andreas Rene Geist and Christian M. Ruff and Petra J. Panak and Melissa A Denecke},
  journal={Inorganic chemistry},
  year={2010},
  volume={49 20},
  pages={
          9627-35
        }
}
With the aim of better understanding the selectivity of the established system 2,6-ditriazinylpyridine (BTP) for actinide(III)/lanthanide(III) separations, a related model system was synthesized and studied. The N donor complexing ligand 6-(3,5-dimethyl-1H-pyrazol-1-yl)-2,2'-bipyridine (dmpbipy) was synthesized having a fused N heterocycle ring structure modified from the BTP partitioning ligand, and its extraction performance and selectivity for trivalent actinide cations over lanthanides was… CONTINUE READING