5-Arylidene Derivatives of Meldrum’s Acid as Synthons in Pyrano[4,3-b]pyran Synthesis

  title={5-Arylidene Derivatives of Meldrum’s Acid as Synthons in Pyrano[4,3-b]pyran Synthesis},
  author={A. Pałasz and K. Jelska and M. Oż{\'o}g and P. Serda},
  journal={Monatshefte f{\"u}r Chemie - Chemical Monthly},
Summary.The reactions of 5-arylidene derivatives of Meldrum’s acid with ethyl vinyl ether or N-vinyl-2-oxazolidinone yielded trans-trans-(2,4:4,7)-pyrano[4,3-b]pyrans, cis-trans-(2,4:4,7)-pyrano[4,3-b]pyrans, or diastereoisomeric mixtures of pyrano[4,3-b]pyrans and reactions with 3,4-dihydro-2H-pyran afforded Michael adducts. The reactions of 5-arylidene derivatives of Meldrum’s acid with cyanoacetic acid derivatives do not provide appropriate pyrans. 
15 Citations
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  • 2005
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