4-Coumarate:coenzyme A ligase has the catalytic capacity to synthesize and reuse various (di)adenosine polyphosphates.

@article{PietrowskaBorek20034CoumaratecoenzymeAL,
  title={4-Coumarate:coenzyme A ligase has the catalytic capacity to synthesize and reuse various (di)adenosine polyphosphates.},
  author={Małgorzata Pietrowska-Borek and H P Stuible and Erich Kombrink and Andrzej Guranowski},
  journal={Plant physiology},
  year={2003},
  volume={131 3},
  pages={1401-10}
}
4-Coumarate:coenzyme A ligase (4CL) is known to activate cinnamic acid derivatives to their corresponding coenzyme A esters. As a new type of 4CL-catalyzed reaction, we observed the synthesis of various mono- and diadenosine polyphosphates. Both the native 4CL2 isoform from Arabidopsis (At4CL2 wild type) and the At4CL2 gain of function mutant M293P/K320L, which exhibits the capacity to use a broader range of phenolic substrates, catalyzed the synthesis of adenosine 5'-tetraphosphate (p(4)A) and… CONTINUE READING
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