4,2-Ribbon like ferromagnetic cyano-bridged Fe(III)2Ni(II) chains: a magneto-structural study.

@article{Toma200742RibbonLF,
  title={4,2-Ribbon like ferromagnetic cyano-bridged Fe(III)2Ni(II) chains: a magneto-structural study.},
  author={Luminita Marilena Toma and Rodrigue Lescou{\"e}zec and Santiago Uriel and Rosa Llusar and Catalina Ruiz-P{\'e}rez and Jacqueline Vaissermann and Francesc Lloret and Miguel Julve},
  journal={Dalton transactions},
  year={2007},
  volume={33},
  pages={3690-8}
}
The low-spin iron(III) complex AsPh(4)[Fe(III)(bpy)(CN)(4)].CH(3)CN (1) [AsPh(4) = tetraphenylarsonium cation] and the heterobimetallic chains [{Fe(III)(L)(CN)(4)}(2)Ni(II)(H(2)O)(2)].4H(2)O with L = bpy (2) and phen (3) [bpy = 2,2'-bipyridine and phen = 1,10-phenanthroline] have been prepared and their structures determined by X-ray diffraction methods. The structure of 1 consists of mononuclear [Fe(bpy)(CN)(4)](-) anions, tetraphenylarsonium cations and acetonitrile molecules of… CONTINUE READING