33S hyperfine interactions in H2S and SO2 and revision of the sulfur nuclear magnetic shielding scale.

Abstract

Using the Lamb-dip technique, the hyperfine structure in the rotational spectra of H2(33)S and (33)SO2 has been resolved and the corresponding parameters--that is, the sulfur quadrupole-coupling and spin-rotation tensors--were determined. The experimental parameters are in good agreement with results from high-level coupled-cluster calculations, provided… (More)
DOI: 10.1063/1.4849177

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