2-azabenzonorbornanes from 7-azabenzonorbornanols by a nitrogen-directed neophyl-type radical rearrangement.

Abstract

[reaction: see text] Barton deoxygenation of 7-azabenzonorbornanols leads to a synthetically useful neophyl-like rearrangement to give 2-azabenzonorbornane derivatives in 64-90% yields. 

Cite this paper

@article{Hodgson20022azabenzonorbornanesF7, title={2-azabenzonorbornanes from 7-azabenzonorbornanols by a nitrogen-directed neophyl-type radical rearrangement.}, author={David M Hodgson and Magnus W P Bebbington and Paul B Willis}, journal={Organic letters}, year={2002}, volume={4 24}, pages={4353-6} }