2-(4-Sulfamoylphen­yl)hydrazin-1-ium chloride


The hydrazinium residue in the cation of the title salt, C(6)H(10)N(3)O(2)S(+)·Cl(-), is twisted out of the plane of the benzene ring to which it is attached [N-N-C-C torsion angle = 25.9 (2)°] and the amino group is almost perpendicular to the benzene ring [N-S-C-C torsion angle = 88.71 (16)°]. In the crystal, the cations are linked by N-H⋯O hydrogen bonds and π-π inter-actions [ring centroid distance = 3.7280 (11) Å], forming layers in the bc plane that are connected by N-H⋯Cl hydrogen bonds.

DOI: 10.1107/S1600536812011452

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@inproceedings{Asiri201224Sulfamoylphenylhydrazin1iumC, title={2-(4-Sulfamoylphen­yl)hydrazin-1-ium chloride}, author={Abdullah M. Asiri and Hassan M. Faidallah and Khalid A. Alamry and Seik Weng Ng and Edward R T Tiekink}, booktitle={Acta crystallographica. Section E, Structure reports online}, year={2012} }